网曝吃瓜

144.听Xu, P.; Wang, D.-S.; Zhu, Z.-Y.; Zhang, X. P.听淓nantioselective Radical Dearomative Conjugate Amination Enabled by Co(II)-Based Metalloradical Catalysis.澨�Nat. Catal.听2025, 8, 1051�1061. []

143.听Wang, D.-S.; Zhang, X. P.听Cobalt-Catalyzed Asymmetric Radical Reactions.听In听Catalytic Asymmetric Radical Reactions,听Liu, X.-Y.; Liu, G.听Eds.;听2025; pp听23�76. []

142.听Lee, W.-C. C.; Wang, D.-S.; Deb, A.; Zhu, Y.; Zhang, X. P. 淎symmetric C揌 Amination via Fe(III)-Metalloradical Catalysis Featuring 伪-Fe(IV)-Aminyl Radicals as Key Intermediates澨�J. Am. Chem. Soc.听2025, 147, 24001�24013. []

141.听Zhu, Y.-L.; Lee, W.-C. C.; Zhang, X. P. 淐atalytic Metalloradical System for Radical 1,6-C(sp3)揌 Amination with Concurrent Control of Site-, Chemo-, and Enantio-selectivity澨�J. Am. Chem. Soc.听2025, 147, 15755�15766. []

140.听Lee, W.-C. C.; Zhang, X. P. 淢etalloradical Catalysis: General Approach for Controlling Reactivity and Selectivity of Homolytic Radical Reactions澨�Angew. Chem. Int. Ed.听2024,听63, e202320243. []

139.听Lee, W.-C. C.; Zhang, X. P. 淎symmetric Radical Aziridination of Alkenes澨�Trends Chem.听2024,听6,听95�96. [][]

138.听Xu, H.; Wang, D.-S.; Zhu, Z.-Y.; Deb, A.; Zhang, X. P. 淣ew Mode of Asymmetric Induction for Enantioselective Radical听N-Heterobicyclization via Kinetically Stable Chiral Radical Center澨�Chem听2024,听10,听283�298. []

137.听Wang, D.-S.; Zhang, X. P. Oxidation: C鈹�N Bond Formation by Oxidation (Aziridines). In Comprehensive Chirality, Second ed.; Cossy, J. Ed.; Elsevier,听2024; pp 158�179. []

136.听Lee, W.-C. C.; Zhang, X. P. 淚ron(III) Porphyrin Complexes as Metalloradical Catalysts澨�Nat. Chem.听2023,听15,听1499�1500. []

135.听Lee, W.-C. C.; Wang, D.-S.; Zhu, Y.-L.; Zhang, X. P. 淚ron(III)-Based Metalloradical Catalysis for Asymmetric Cyclopropanation via a Stepwise Radical Mechanism澨�Nat. Chem.听2023,听15,听1569�1580. [] []

134.听Lee, W.-C. C.;犔齏ang, J.-Y.;犔齔hu, Y.-L.; Zhang, X. P. 淎symmetric Radical Bicyclization for Stereoselective Construction of Tricyclic Chromanones and Chromanes with Fused Cyclopropanes澨�J. Am. Chem. Soc.听2023,听145,听11622�11632. [] [] []

133.听Xu, P.; Xie, J.-J.; Wang, D.-S.; Zhang, X. P. 淢etalloradical Approach for Concurrent Control in Intermolecular Radical Allylic C鈭扝 Amination澨�Nat. Chem.听2023,听15,听498�507. []

132.听Novaes, L. F. T.; Wang, Y.; Liu, J.-J.; Riart-Ferrer, X.; Lee, W.-C. C.; Fu, N.-K.; Zhang, X. P.; Lin, S. 淓lectrochemical Diazidation of Alkenes Catalyzed by Manganese Porphyrin Complexes with Second-Sphere Hydrogen-Bond Donors澨�ACS Catal.听2022,听12,听14106�14112. []

131.听Lang, K.; Hu, Y.; Lee, W.-C. C.; Zhang, X. P. 淐ombined Radical and Ionic Approach for The Enantioselective Synthesis of听尾-Functionalized Amines from Alcohols澨�Nat. Synth.听2022,听1,听548�557. [] [] []

130.听听Lee, W.-C. C.; Zhang, X. P. 淎symmetric Radical Cyclopropanation of Alkenes澨�Trends Chem.听2022,听4,听850�851. []

129.听听Ke, J.; Lee, W.-C. C.; Wang, X.-X.; Wang, Y.; Wen, X.; Zhang, X. P. 淢etalloradical Activation of In Situ-Generated听伪听-Alkynyldiazomethanes for Asymmetric Radical Cyclopropanation of Alkenes澨�J. Am. Chem. Soc.听2022,听144, 2368�2378. []

128.听听Wang, X.-X.; Zhang, X. P. 淐atalytic Radical Approach for Selective Carbene Transfers via Cobalt(II)-Based Metalloradical Catalysis� In听Transition Metal-Catalyzed Carbene Transformations听2022, 25-66. []

127.听听Wang, J.-Y.; Xie, J.-J.; Lee, W.-C. C.; Wang, D.-S.; Zhang, X. P. 淩adical Differentiation of Two Ester Groups in Unsymmetrical Diazomalonates for Highly Asymmetric Olefin Cyclopropanation澨�Chem Catal.听2022,听2, 330�344. [] [] []

126.听听Zhang, W.-J.; Nafady, A.; Shan, C.; Wojtas, L.; Chen, Y.-S.; Cheng, Q.-G.; Zhang, X. P.; Ma, S.-Q. 淔unctional Porphyrinic Metal-Organic Framework as a New Class of Heterogeneous Halogen Bond Donor Catalyst�听Angew. Chem. Int. Ed.听2021,听60, 24312�24317. []

125.听听Xie, J.-J.; Xu, P.; Zhu, Y.-L.; Wang, J.-Y.; Lee, W.-C. C.; Zhang, X. P. 淣ew Catalytic Radical Process Involving 1,4-Hydrogen Atom Abstraction: Asymmetric Construction of Cyclobutanones澨�J. Am. Chem. Soc.听2021,听143, 11670-11678. []

124.听听Wang, X.-X.; Ke, J.; Zhu, Y.-L.; Deb, A.; Xu, Y.-J.; Zhang, X. P. 淎symmetric Radical Process for General Synthesis of Chiral Heteroaryl Cyclopropanes澨�J. Am. Chem. Soc.听2021,听143, 11121-11129. []

123.听听Zhang, C.-Z.; Wang, D.-S.; Lee, W.-C. C.; McKillop, A. M.; Zhang, X. P. 淐ontrolling Enantioselectivity and Diastereoselectivity in Radical Cascade Cyclization for Construction of Bicyclic Structures�听J. Am. Chem. Soc.听2021,听143, 11130-11140. []

122.听听Lee, W.-C. C. 淢etalloradical Catalysis: A Radically Different Approach for Molecular Construction�听Chem听2021,听7, 1402-1404. []

121.听听Lee, W.-C. C.; Wang, D.-S.; Zhang, C.-Z.; Xie, J.-J.; Li, B.; Zhang, X. P. 淎symmetric Radical Cyclopropanation of Dehydroaminocarboxylates: Stereoselective Synthesis of Cyclopropyl听伪-Amino Acids�听Chem听2021,听7, 1588-1601. []

120.听听Magnuson, Z. L.; Cheng, Q.-G.; Zhang, W.-J.; Chen, Y.-S.; Wojtas, L.; Nafady, A.; Al-Enizi, A. M.; Larsen, R. W.; Zhang, X. P.; Ma, S.-Q. 淭wo Manganese Metalloporphyrin Frameworks Constructed from a Custom-Designed Porphyrin Ligand Exhibiting Selective Uptake of CO2听over CH4听and Catalytic Activity for CO2听Fixation�听Cryst. Growth Des.听2021,听21, 2786�2792. []

119.听听Riart-Ferrer, X.; Sang, P.; Tao, J.-R.; Xu, H.; Jin, L.-M.; Lu, H.-J.; Cui, X.; Wojtas, L.; Zhang, X. P. 淢etalloradical Activation of Carbonyl Azides for Enantioselective Radical Aziridination�听Chem听2021,听7, 1120�1134. []

118.听听Lang, K.; Li, C.-Q.; Kim, I.; Zhang, X. P. 淓nantioconvergent Amination of Racemic Tertiary C-H Bonds�听J. Am. Chem. Soc.听2020,听142, 20902�20911. []

117.听听Jin, L.-M.; Xu, P.; Xie, J.-J.; Zhang, X. P. 淓nantioselective Intermolecular Radical C鈭扝 Amination澨�J. Am. Chem. Soc.听2020,听142, 20828�20836. []

116.听听Hu, Y.; Lang, K.; Li, C.-Q.; Gill, J. B.; Kim, I.; Lu, H.-J.; Fields, K. B.; Marshall, M. K.; Cheng, Q.-G.; Cui, X.; Wojtas, L.; Zhang, X. P. 淓nantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C鈭扝 Amination澨�J. Am. Chem. Soc.听2019,听141, 18160-18169. []

115.听听Lang, K.; Torker, S.; Wojtas, L.; Zhang, X. P. 淎symmetric Induction and Enantiodivergence in Catalytic Radical C揌 Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution澨�J. Am. Chem. Soc.听2019,听141, 12388�12396. []

114.听听Hu, Y.; Lang, K.; Tao, J.-R.; Marshall, M. K.; Cheng, Q.-G.; Cui, X.; Wojtas, L.; Zhang, X. P. 淣ext-Generation D2-Symmetric Chiral Porphyrins for Cobalt(II)-Based Metalloradical Catalysis: Catalyst Engineering by Distal Bridging澨�Angew. Chem. Int. Ed.听2019,听58, 2670�2674. []

113.听听Li, C.-Q.; Lang, K.; Lu, H,-J.; Hu, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. 淐atalytic Radical Process for Enantioselective Amination of C(sp3)-H Bonds澨�Angew. Chem. Int. Ed.听2018,听57, 16837�16841. []

112.听听Wen, X.; Wang, Y.; Zhang, X. P. 淓nantioselective Radical Process for Synthesis of Chiral Indolines by Metalloradical Alkylation of Diverse C(sp3)-H Bonds澨�Chem. Sci.听2018,听9, 5082�5086. []

111.听听Wang, Y.; Wen, X.; Cui, X.; Zhang, X. P. 淓nantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation澨�J. Am. Chem. Soc.听2018,听140, 4792�4796. []

110.听听Wang, Y.; Zhang, X. P. 淸Co(3,5-Di-t-Bu-QingPhyrin)]澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02204. []

109.听听Wang, Y.; Zhang, X. P. 淸Co(3,5-Di-t-Bu-Xu(2�-Naph)Phyrin)]澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02203. []

108.听听Wang, Y.; Zhang, X. P. 淸Co(3,5-Di-t-Bu-ChenPhyrin)]澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02202. []

107.听听Wang, Y.; Zhang, X. P. 淸Co(3,5-Di-t-Bu-IbuPhyrin)]澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02201. []

106.听听Wang, Y.; Zhang, X. P. 淸Co(2,6-DiMeO-ZhuPhyrin)]澨�e-EROS, John Wiley & Sons,听2018;听DOI: 10.1002/047084289X.rn02200. []

105.听听Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. 淎symmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis澨�J. Am. Chem. Soc.听2017,听139, 9164�9167. []

104.听听Xu, X.; Wang, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. 淢etalloradical Activation of听伪-Formyldiazoacetates for Catalytic Asymmetric Radical Cyclopropanation of Alkenes澨�Chem. Sci.听2017,听8, 4347�4351. []

103.听听Wang, Y.; Wen, X.; Cui, X.; Wojtas, L.; Zhang, X. P. 淎symmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis澨�J. Am. Chem. Soc.听2017,听139, 1049�1052. []

102.听听Pegis, M. L.; McKeown, B. A.; Kumar, N.; Lang, K.; Wasylenko, D. J.; Zhang, X. P.; Raugei, S.; Mayer, J. M. 淗omogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions澨�ACS Cent. Sci.听2016,听2, 850�856. []

101.听听Jiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. 淚ntramolecular Radical Aziridination of Allylic Sulfamoyl Azides via Co(II)-Based Metalloradical Catalysis: Effective Construction of Strained heterobicyclic Structures澨�Angew. Chem. Int. Ed.听2016,听55, 11604�11608. []

100.听听Lu, H.-J.; Lang, K.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. 淚ntramolecular 1,5-C(sp3)揌 Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides澨�Chem. Sci.听2016,听7, 6934�6939. []

99.听听Liu, Q.-J.; Wang, L.-J.; Kang, Q.-K.; Zhang, X. P.; Tang, Y. 淐y-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals澨�Angew. Chem. Int. Ed.听2016,听55, 9220�9223. []

98.听听Cui, X.; Zhang, X. P. 淐揅 Bond Formation Using Carbenes� In听Science of Synthesis: Catalytic Transformations via C揌 Activation听series; eds. Yu, J. -Q.; Thieme,听2016, Vol. 2, pp. 63�94. []

97.听听Liu, Q.-J.; Yan, W.-G.; Wang, L.-J.; Zhang, X. P.; Tang, Y. 淥ne-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles澨�Org. Lett.听2015,听17, 4014�4017. []

96.听听Goswami, M.; Lyaskovskyy, V.; Domingos, S. R.; Buma, W. J.; Woutersen, S.; Troeppner, O.; Ivanovic-Burmazovic, I.; Lu, H.-J.; Cui, X.; Zhang, X. P.; Reijerse, E. J.; DeBeer S.; van Schooneveld, M. M.; Pfaff, F.; Ray, K.; de Bruin, B. 淐haracterization of Porphyrin-Co(III)-楴itrene Radical� Species Relevant in Catalytic Nitrene Transfer Reactions澨�J. Am. Chem. Soc.听2015,听137, 5468�5479. []

95.听听Subbarayan, V.; Jin, L.-M., Cui, X.; Zhang, X. P. 淩oom Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis澨�Tetrahedron Lett.听2015,听56, 3431�3434. []

94.听听Cui, X.; Xu, X.; Jin, L.-M.; Wojtas, L.; Zhang, X. P. 淪tereoselective Radical C揌 Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis澨�Chem. Sci.听2015.听6, 1219�1224. []

93.听听Jin, C.-Y., Decker, A. M.; Huang, X.-P.; Gilmour, B. P.; Blough, B. E.; Roth, B. L.; Hu, Y.; Gill, J. B.; Zhang, X. P. 淪ynthesis, Pharmacological Characterization, and Structure-Activity Relationship Studies of Small Molecular Agonists for the Orphan GPR88澨�ACS Chem. Neurosci.听2014,听5, 576�587. []

92.听听Lu, H.-J.; Li, C.-Q.; Jiang, H.-L.; Lizardi, C. L.; Zhang, X. P. 淐hemoselective Amination of Propargylic C(sp3)鈭扝 Bonds via Co(II)-Based Metalloradical Catalysis澨�Angew. Chem. Int. Ed.听2014,听53, 7028�7032. []

91.听听Tao, J.-R.; Jin, L.-M.; Zhang, X. P. 淪ynthesis of Chiral听N-Phosphoryl Aziridines through Enantioselective Aziridination of Alkenes With Phosphoryl Azide via Co(II)-Based Metalloradical Catalysis澨�Beilstein J. Org. Chem.听2014,听10, 1282�1289. []

90.听听Ruppel, J. V.; Cui, X.; Xu, X.; Zhang, X. P. 淪tereoselective Intramolecular Cyclopropanation of alpha-Diazoacetates via Co(II)-Based Metalloradical Catalysis澨�Org. Chem. Front.听2014,听1, 515�520. []

89.听听Jin, L.-M.; Lu, H.-J.; Cui, Y.; Lizardi, C. L.; Arzua, T. N.; Wojtas, L.; Cui, X.; Zhang, X. P. 淪elective Radical Amination of Aldehydic C(sp2)扝 Bonds with Fluoroaryl Azides via Co(II)-Based Metalloradical Catalysis: Synthesis of听N-Fluoroaryl Amides from Aldehydes under Neutral and Nonoxidative Conditions澨�Chem. Sci.听2014,听5, 2422�2427. []

88.听听Paul, N. D.; Mandal, S.; Otte, M.; Cui, X.; Zhang, X. P.; de Bruin, B. 淎 Metalloradical Approach to听2H-Chromenes澨�J. Am. Chem. Soc.听2014,听136, 1090�1096. []

87.听听Cui, X.; Zhang, X. P. 淎symmetric C揌 Functionalization by Transition Metal-Catalyzed Carbene Transfer Reactions� In听Comprehensive Organic Synthesis II (Second Edition)听Eds. Knochel, P.; Molander, G.; Amsterdam: Elsevier,听2014, Vol. 7, pp. 86�120. []

86.听听Maza, W. A.; Vetromile, G. M.; Kim, C.-S.; Xu, X.; Zhang, X. P.; Larsen, R. W. 淪pectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II)porphyrins澨�J. Phys. Chem. A.听2013,听117, 11308�11315. []

85.听听Xu, X.; Zhu, S.-F.; Cui, X.; Wojtas, L.; Zhang, X. P. 淐obalt(II)-Catalyzed Asymmetric Olefin Cyclopropanation with a-Ketodiazoacetates澨�Angew. Chem. Int. Ed.听2013,听52, 11857�11861. [] [Highlighted in听]

84.听听Paul, N. D.; Lu, H.-J.; Zhang, X. P.; de Bruin, B. 淐arbene Radicals in Cobalt(II) Porphyrin-Catalyzed Carbene Carbonylation Reactions: A Catalytic Approach to Ketenes澨�Chem. Eur. J.听2013,听19, 12953�12958. []

83.听听Liu, L.; Xie, H.; Bostic, H. E.; Jin, L.-M.; Best, D. B.; Zhang, X. P.; Zhan, W. 淓ffects of Oriented Surface Dipole on Photoconversion Efficiency in an Alkane/Lipid-Hybrid-Bilayer-Based Photovoltaic Model System澨�ChemPhysChem听2013,听14, 2777�2785. []

82.听听Cui, X.; Zhang, X. P. 淐obalt-Mediated Carbene Transfer Reactions� In听Contemporary Carbene Chemistry; eds. Moss, R. A.; Doyle, M. P.; John Wiley & Sons,听2013, Chapter 15, 491�525. []

81.听听Jin, L.-M.; Xu, X.; Lu, H.; Cui, X.; Wojtas, L.; Zhang, X. P. 淓ffective Synthesis of Chiral听N-Fluoroaryl Aziridines via Enantioselective Aziridination of Alkenes with Fluoroaryl Azides澨�Angew. Chem. Int. Ed.听2013,听52, 5309�5313. [] [Highlighted in听] [Highlighted in听]

80.听听Cui, X.; Xu, X.; Wojtas, L.; Kim, M. M.; Zhang, X. P. 淩egioselective Synthesis of Multisubstituted Furans via Metalloradical Cyclization of Alkynes with alpha-Diazocarbonyls: Construction of Functionalized alpha-Oligofurans澨�J. Am. Chem. Soc.听2012,听134, 19981�19984. [] [Highlighted in听] [Highlighted in听]

79.听听Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. 淪tereoselective Radical Amination of Electron-Deficient C(sp3)揌 Bonds by Co(II)-Based Metalloradical Catalysis: Synthesis of alpha-Amino Acid Derivatives via alpha-C揌 Amination of Esters and Amides澨�Org. Lett.听2012,听14, 5158�5161. []

78.听听Meng, L.; Cheng, Q.; Kim, C.-S.; Gao, W.-Y.; Wojtas, L.; Chen, Y.-S.; Zaworotko, M. J.; Zhang, X. P.; Ma, S.-Q. 淐rystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker澨�Angew. Chem. Int. Ed.听2012,听51, 10082�10085. [] [Selected as听]

77.听听Jiang, H.-L.; Zhang, X. P. 淥xidation: C鈹�N Bond Formation by Oxidation (Aziridines)� In听Comprehensive Chirality; eds. Carreira, E. M.; Yamamoto, H.; Amsterdam: Elsevier,听2012, Vol. 5, pp. 168�182. []听

76.听听Wang, X.-S.; Chrzanowski, M.; Gao, W.-Y.; Kim, C.-S.; Wojtas, L.; Chen, Y.-S.; Zhang, X. P.; Ma, S.-Q. 淨uest for Highly听Porous Metal-Metalloporphyrin Framework Based upon A Custom-Designed听Octatopic Porphyrin Ligand澨�Chem. Commun.听2012,听48, 7173�7175. []

75.听听Hu, Y.; Zhang, X. P. 淪elective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents澨�Top. Curr. Res.听2012,听327, 147�162. []

74.听听Zhu, S.-F.; Cui, X.; Zhang, X. P. 淟igand Effect on Cobalt(II)-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Approaching High Stereoselectivity through Modular Design of D2-Symmetric Chiral Porphyrins澨�Eur. J. Inorg. Chem.听2012, 430�434. []

73.听听Burda, W. N.; Fields, K. B.; Gill, J. B.; Burt, R.; Shepherd, M.; Zhang, X. P.; Shaw, L. N. 淣eutral Metallated and Meso-Substituted Porphyrins as Antimicrobial Agents Against Gram-Positive Pathogens澨�Eur. J. Clin. Microbiol. Infect. Dis.听2012,听31, 327�335. []

72.听听Cui, X.; Zhang, X. P. 淚ron(III) meso-Tetraphenylporphine Chloride澨�e-EROS, John Wiley & Sons,听2012;听DOI: 10.1002/047084289X.rn01388. []

71.听听Wang, X.-S.; Meng, L.; Cheng, Q.-G.; Kim, C.-S.; Wojtas, L.; Chrzanowski, M.; Chen, Y.-S.; Zhang, X. P.; Ma, S.-Q. 淎 Three-Dimensional Porous Metal-Metalloporphyrin Framework Consisting of Nanoscopic Polyhedral Cages with a High Density of Open Metal Sites澨�J. Am. Chem. Soc.听2011,听133, 16322�16325. []

70.听听Lu, H.-J.; Jiang, H.-L.; Hu, Y.; Wojtas, L.; Zhang, X. P. 淐hemoselective Intramolecular Allylic C揌 Amination over C=C Aziridination through Co(II)-Based Metalloradical Catalysis澨�Chem. Sci.听2011,听2, 2361�2366. [] [Highlighted in听]

69.听听Xu, X.; Lu, H.-J.; Ruppel, J. V.; Cui, X.; de Mesa, S. L.; Wojtas, L.; Zhang, X. P. 淗ighly Asymmetric Intramolecular Cyclopropanation of Acceptor-Substituted Diazoacetates by Co(II)-Based Metalloradical Catalysis: Iterative Approach for Development of New Generation Catalysts澨�J. Am. Chem. Soc.听2011,听133, 15292�15295. [] [Highlighted in听]

68.听听Lyaskovskyy, V.; Suarez, A. I. O.; Lu, H.-J.; Jiang, H.-L.; Zhang, X. P.; de Bruin, B. 淢echanism of Cobalt(II) Porphyrin-Catalyzed C揌 Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of Cobalt(III)-Nitrene Key Intermediates澨�J. Am. Chem. Soc.听2011,听133, 12264�12273. []

67.听听Lu, H.-J.; Dzik, W. I.; Xu, X.; Wojtas, L.; de Bruin, B.; Zhang, X. P. 淓xperimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation澨�J. Am. Chem. Soc.听2011,听133, 8518�8521. []

66.听听Belof, J. L.; Cioce, C. R.; Xu, X.; Zhang, X. P.; Space, B.; Woodcock, H. L. 淐haracterization of Tunable Radical Metal-Carbenes: Key Intermediates in Catalytic Cyclopropanation�,听Organometallics听2011,听30, 2739�2746. []

65.听听Dzik, W. I.; Zhang, X. P.; de Bruin, B. 淭he Redox Non-Innocence of Carbene Ligands: Carbene Radicals in (Catalytic) C-C Bond Formation澨�Inorg. Chem.听听2011,听50, 9896�9903. []

64.听听Uygun, A.; Myjavcova, R.; Yavuz, A. G.; Ruppel. J. V.; Fields, K. B.; Frankhauser, A.; Zhang, X. P.; Bhethanbotla, V. R.; Bednar, P. 淓lectrochemical Polymerization and Investigation of Properties of Poly(5-(4�-aminophenylamino)-10,20-diphenylporphyrin)澨�Electroanalysis听2011,听23, 1158�1167. []

63.听听Suarez, A. I. O.; Jiang, H.-L.; Zhang, X. P.; de Bruin, B. 淭he Radical Mechanism of Cobalt(II) Porphyrin-Catalyzed Olefin Aziridination and the Importance of Cooperative H-Bonding澨�Dalton Trans.听听2011,听40, 5697�5705. []

62.听听Cui, X.; Xu, X.; Lu, H.-J.; Zhu, S.-F.; Wojtas, L.; Zhang, X. P. 淓nantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis澨�J. Am. Chem. Soc.听2011,听133, 3304�3307. [] [Highlighted in听]

61.听听Lu, H.-J.; Zhang, X. P. 淐atalytic C揌 Functionalization by Metalloporphyrins: Recent Development and Future Directions澨�Chem. Soc. Rev.听2011,听40, 1899�1909. []

60.听听Fields, K. B.; Engle, J. T.; Sripothongnak, S.; Kim, C.-S.; Zhang, X. P.; Ziegler, C. J. 淐obalt Carbaporphyrin-Catalyzed Cyclopropanation澨�Chem. Commun.听2011,听47, 749. []听听

59.听听Lu, H.-J.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. 淪elective Intramolecular C揌 Amination via Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions澨�Angew. Chem. Int. Ed.听2010,听49, 10192�10196. [] [Selected as听][Highlighted in听]

58.听听Zhan, W.; Jiang, K.; Smith, M. D.; Bostic, H. E.; Best, M. D.; Auad, M. L.; Ruppel, J. V.; Kim, C.-S.; Zhang, X. P. 淧hotocurrent Generation from Porphyrin/Fullerene Complexes Assembled in a Tethered Lipid Bilayer澨�Langmuir听2010, 26, 15671�15679. []

57.听听Hilker, B.; Fields, K. B.; Stern, A.; Space, B.; Zhang, X. P.; Harmon, J. P. 淒ielectric Analysis of Poly(methyl methacrylate) Zinc(II) Mono-pinacolborane Diphenylporphyrin Composites澨�Polymer听2010, 51, 4790�4805. []

56.听听Zhu, S.-F.; Xu, X.; Perman, J. A.; Zhang, X. P. 淎 General and Efficient Cobalt(II)-Based Catalytic System for Highly Stereoselective Cyclopropanation of Alkenes with a-Cyano-Diazoacetates澨�J. Am. Chem. Soc.听2010,听132, 12796�12799. [] [Highlighted in听] [Highlighted in听]

55.听听Dzik, W. I.; Xu, X.; Zhang, X. P.; Reek, J. N. H.; de Bruin, B. 淐arbene Radicals� in CoII(por)-Catalyzed Olefin Cyclopropanation澨�J. Am. Chem. Soc.听2010,听132, 10891�10902. []

54.听听Lu, H.-J.; Tao, J.-R.; Jones, J. E.; Wojtas, L.; Zhang, X. P. 淐o(II)-Catalyzed Intramolecular C揌 Amination of Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates澨�Org. Lett.听2010,听12,听1248�1251. [] [Highlighted in听]

53.听听Lu, H.-J.; Subbarayan, V.; Tao, J.; Zhang, X. P. 淐obalt-Catalyzed Intermolecular Benzylic C揌 Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)澨�Organometallics听2010,听29, 389�393. []

52.听听Ruppel, J. V.; Fields, K. B.; Snyder, N. L.; Zhang, X. P. �Metalloporphyrin-Catalyzed Asymmetric Atom/Group Transfer Reactions� In听Handbook of Porphyrin Science; eds. Kadish, K. M.; Smith, K. M.; Guilard, R.; World Scientific,听2010, Vol. 10, Chapter 43, pp. 1�84. []

51.听听Fields, K. B.; Ruppel, J. V.; Snyder, N. L.; Zhang, X. P. �Porphyrin Functionalization via Carbon-Heteroatom Cross-Coupling Reactions� In听Handbook of Porphyrin Science; eds. Kadish, K. M.; Smith, K. M.; Guilard, R.; World Scientific,听2010, Vol. 3, Chapter 13, pp. 367�428. []

50.听听Subbarayan, V.; Ruppel, J. V.; Zhu, S.-F.; Perman, J. A.; Zhang, X. P. 淗ighly Asymmetric Cobalt-Catalyzed Aziridination of Alkenes with Trichloroethoxysulfonyl Azide (TcesN3)澨�Chem. Commun.听2009,听4266�4268. []

49.听听Ruppel, J. V.; Gauthier, T. J.; Snyder, N. L.; Perman, J. A.; Zhang, X. P. 淎symmetric Cobalt-Catalyzed Cyclopropanation with Succinimidyl Diazoacetate: General Synthesis of Optically Active Cyclopropyl Carboxamides澨�Org. Lett.听2009,听11, 2273�2276. [] [Highlighted in听]听

48.听听Zhu, S.-F.; Zhang, X. P. 淐obalt(II) Acetate澨�e-EROS, John Wiley & Sons,听2009; DOI: 10.1002/047084289X.rc182.pub2. []

47.听听Zhu, S.-F.; Perman, J. A.; Zhang, X. P. 淎cceptor/Acceptor-Substituted Diazo Reagents for Carbene Transfers: Cobalt-Catalyzed Asymmetric (Z)-Cyclopropanation of Alkenes with a-Nitro-Diazoacetates澨�Angew. Chem. Int. Ed.听2008, 47, 8460�8463. [] [Highlighted in听] [Highlighted in听]

46.听听Jones, J. E.; Ruppel, J. V.; Gao, G.-Y.; Thomas, M. M.; Zhang, X. P. 淐obalt-Catalyzed Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide澨�J. Org. Chem.听2008,听73, 7260�7265. []

45.听听Gao, G.-Y.; Ruppel, J. V.; Fields, K. B.; Xu, X.; Chen, Y.; Zhang, X. P. 淪ynthesis of Diporphyrins via Palladium-Catalyzed C揙 Bond Formation: Effective Access to Chiral Diporphyrins澨�J. Org. Chem.听2008,听73, 4855�4858. []

44.听听Ruppel, J. V.; Jones, J. E.; Huff, C. A.; Kamble, R. M.; Chen, Y.; Zhang, X. P. 淎 Highly Effective Cobalt Catalyst for Olefin Aziridination with Azides: Hydrogen Bonding-Guided Catalyst Design澨�Org. Lett.听2008,听10, 1995�1998. []

43.听听Zhu, S.; Ruppel, J. V.; Lu, H.; Wojtas, L.; Zhang, X. P. 淐obalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization澨�J.听Am. Chem. Soc.听2008,听130, 5042�5043. [] [Highlighted in听] [Highlighted in听]

42.听听Gao, G. Y.; Ruppel, J. V.; Allen, D. B.; Chen, Y.; Zhang, X. P. 淪ynthesis of beta-Functionalized Porphyrins via Palladium-Catalyzed Carbon揌eteroatom Bond Formations: Expedient Entry into beta-Chiral Porphyrins澨�J. Org. Chem.听2007,听72, 9060�9066. []

41.听听Harden, J. D.; Ruppel, J. V.; Gao, G.-Y.; Zhang, X. P. 淐obalt-Catalyzed Intermolecular C揌 Amination with Bromamine-T as Nitrene Source澨�Chem. Comm.听2007,听4644�4646. []

40.听听Ruppel, J. V.; Kamble, R. M.; Zhang, X. P. 淐obalt-Catalyzed Intramolecular C揌 Amination with Arylsulfonyl Azides澨�Org. Lett.听2007,听9, 4889�4892. []

39.听听Chen, Y.; Ruppel, J. V.; Zhang, X. P. 淐obalt-Catalyzed Asymmetric Cyclopropanation of Electron-Deficient Olefins澨�J.听Am. Chem. Soc.听2007,听129, 12074�12075. [] [Highlighted in听] [Highlighted in听] [Highlighted in听]

38.听听Chen, Y.; Zhang, X. P. 淎symmetric Cyclopropanation of Styrenes Catalyzed by Metal Complexes of听D2-Symmetrical Chiral Porphyrin: Superiority of Cobalt over Iron澨�J. Org. Chem.听2007,听72, 5931�5934. [] [Highlighted in听]

37.听听Gao, G.-Y.; Jones, J. E.; Vyas, R.; Harden, J. D.; Zhang, X. P. 淐obalt-Catalyzed Aziridination with Diphenylphosphoryl Azide (DPPA): Direct Synthesis of听N-Phosphorous-Substituted Aziridines from Alkenes澨�J. Org. Chem.听2006,听71, 6655�6658. []

36.听听Chen, Y.; Zhang, X. P. 淭rans Effect on Cobalt Porphyrin Catalyzed Asymmetric Cyclopropanation澨�Synthesis听2006,听No.10, 1697�1700. (Invited Contribution to Special Topic) []

35.听听Gao, G.-Y.; Harden, J. D.; Zhang, X. P. 淐obalt-Catalyzed General and Efficient Aziridination of Alkenes澨�Org. Lett.听2005,听7, 3191�3193. []

34.听听Chen, Y.; Gao, G.-Y.; Zhang, X. P. 淧alladium-Mediated Synthesis of Novel听meso-Chiral Porphyrins for Cobalt-Catalyzed Cyclopropanation澨�Tetrahedron Lett.听2005,听46, 4965�4969. []

33.听听Baskaran, D.; Mays, J. W.; Zhang, X. P.; Bratcher, M. S. 淐arbon Nanotubes with Covalently Linked Porphyrin Antennae: Photoinduced Electron Transfer澨�J.听Am. Chem. Soc.听2005,听127, 6916�6917. []

32.听听Gao, G.-Y.; Colvin, A. J.; Chen, Y.; Zhang, X. P. 淪ynthesis of听meso-Arylsulfanyl- and Alkylsulfanyl-Substituted Porphyrins via Palladium-Mediated C揝 Bond Formation澨�J. Org. Chem.听2004,听69, 8886�8892. []

31.听听Chen, Y.; Fields, K. B.; Zhang, X. P. 淏romoporphyrins as Versatile Synthons for Modular Construction of Chiral Porphyrins: Cobalt-Catalyzed Highly Enantioselective and Diastereoselective Cyclopropanation澨�J.听Am. Chem. Soc.听2004,听126, 14718�14719.听[] [Highlighted in听]

30.听听Vyas, R.; Gao, G.-Y.; Harden, J. D.; Zhang, X. P. 淚ron(III) Porphyrin-Catalyzed Aziridination of Alkenes with Bromamine-T as Nitrene Source澨�Org. Lett.听2004,听6, 1907�1910. []

29.听听Gao, G.-Y.; Chen, Y.; Zhang, X. P. 淕eneral Synthesis of听meso-Amidoporphyrins via Palladium-Catalyzed Amidation澨�Org. Lett.听2004,听6, 1837�1840. []

28.听听Chen, Y.; Zhang, X. P. 淰itamin B12听Derivatives as Natural Asymmetric Catalysts: Enantioselective Cyclopropanation of Alkenes澨�J. Org. Chem.听2004,听69, 2431�2435.听[]

27.听听Lee, M.-Y.; Chen, Y.; Zhang, X. P. 淕eneral and Selective Olefination of Aldehydes and Ketones Catalyzed by a Cobalt(II) Porphyrin Complex澨�Organometallics听2003,听22, 4905�4909.听[]

26.听听Huang, L.; Chen, Y.; Gao, G.-Y.; Zhang, X. P. 淒iastereoselective and Enantioselective Cyclopropanation of Alkenes Catalyzed by Cobalt Porphyrins澨�J. Org. Chem.听2003,听68, 8179�8184.听[]

25.听听Gao, G.-Y.; Colvin, A. J.; Chen, Y.; Zhang, X. P. 淰ersatile Synthesis of听meso-Aryloxy- and Alkoxy-Substituted Porphyrins via Palladium-Catalyzed C揙 Cross-Coupling Reactions澨�Org. Lett.听2003,听5, 3261�3264.听[]

24.听听Gao, G.-Y.; Chen, Y.; Zhang, X. P. 淕eneral and Efficient Synthesis of Arylamino- and Alkylamino-Substituted Diphenylporphyrins and Tetraphenylporphyrins via Palladium-Catalyzed Multiple Amination Reactions澨�J. Org. Chem.听2003,听68, 6215�6221.听[]

23.听听Chen, Y.; Huang, L.; Zhang, X. P. 淎cid-Promoted Olefination of Ketones by Iron(III) Porphyrin Complex澨�Org. Lett.听2003,听5, 2493�2496.听[]

22.听听Chen, Y.; Huang, L.; Zhang, X. P. 淓fficient and Stereoselective Synthesis of beta-Trifluoromethyl-alpha, beta-Unsaturated Esters via Iron(III) Porphyrin-Catalyzed Olefination of Ketones澨�J. Org. Chem.听2003,听68, 5925�5929.听[]

21.听听Chen, Y.; Zhang, X. P. 淔acile and Efficient Synthesis of听meso-Arylamino- and Alkylamino-Substituted Porphyrins via Palladium-Catalyzed Amination澨�J. Org. Chem.听2003,听68, 4432�4438.听[]

20.听听Chen, Y.; Huang, L.; Ranade, M. A.; Zhang, X. P. 淚ron(III) and Ruthenium(II) Porphyrin Complexes-Catalyzed Selective Olefination of Aldehydes with Ethyl Diazoacetate澨�J. Org. Chem.听2003,听68, 3714�3717.听[]

19.听听Cui, W.; Zhang, X. P.; Wayland, B. B. 淏imetallo-Radical Carbon-Hydrogen Bond Activation of Methanol and Methane澨�J.听Am. Chem. Soc.听2003,听125, 4994�4995.听[]

18.听听Yin, J-J.; Rainka, M. P.; Zhang, X.-X.; Buchwald, S. L. 淎 Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination澨�J.听Am. Chem. Soc.听2002,听124,听1162�1163. []

17.听听Zhang, X.-X.; Harris, M. C.; Sadighi, J. P.; Buchwald, S. L. 淭he Use of Palladium Chloride as A Precatalyst for the Amination of Aryl Bromides澨�Can.听J. Chem.听2001,听79, 1799�1805. []